Kumamoto Conv. of JPI (50th Petroleum-Petrochemical Symposium of JPI)
Nov 12 - Nov 13, 2020KUMAMOTO-JO HALL
Kumamoto Conv. of JPI (50th Petroleum-Petrochemical Symposium of JPI)
Nov 12 - Nov 13, 2020KUMAMOTO-JO HALL
[1B03]Counter Cation-dependent Thermal Stability and Methane Conversion Reactivity of Dianionic Metal Sulfide Clusters
○Takeshi Matsumoto1,2, Kazuto Kurihara3, Ryota Osuga1, Shuhei Yasuda1, Junko N. Kondo1, Akinobu Nakada3, Ho-Chol Chang3, Toshiyuki Yokoi1(1. Tokyo Institute of Technology, 2. JST-PRESTO, 3. Chuo University)
In this work, to design and create the transition metal sulfide cluster-based methane conversion reaction, we investigated the thermal stability and reactivity of the dianionic metal sulfide cluster with methane. As a result, the different thermal stability of the dianionic clusters dependent upon the type of the coexistent counter cation could be observed. The detailed character of the dianionic metal sulfide cluster, together with the reactivity with methane will be presented.