Hakodate Conv. of JPI (51st Petroleum-Petrochemical Symposium of JPI)
Nov 11 - Nov 12, 2021Hakodate Arena/Hakodate Citizen Hall and Online meeting
Hakodate Conv. of JPI (51st Petroleum-Petrochemical Symposium of JPI)
Nov 11 - Nov 12, 2021Hakodate Arena/Hakodate Citizen Hall and Online meeting
[1A11]Local structure of In-hydride species in zeolite and its reactivity for C2H6 dehydrogenation.
○Shunsaku Yasumura1, Takashi Toyao1,2, Zen Maeno1, Ken-ichi Shimizu1,2(1. Institute for catalysis, Hokkaido University, 2. Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University)
In交換CHA型ゼオライトを高温H2雰囲気下で処理すると，ゼオライト内In ヒドリド種が生成し，エタン脱水素の活性点として働くことを見出した．In-CHAはエタン脱水素反応に優れた選択性と耐久性を示した．IR分光法，速度論的検討及び遷移状態計算から，In-CHAの活性点は[InH2]+であることを明らかにした．
Keywords:
In-hydride,C2H6 dehydrogenation,CHA zeolite