Nagano Conv. of JPI (52nd Petroleum-Petrochemical Symposium of JPI)
Oct 27 - Oct 28, 2022JA Naganoken Buildg.
Nagano Conv. of JPI (52nd Petroleum-Petrochemical Symposium of JPI)
Oct 27 - Oct 28, 2022JA Naganoken Buildg.
[1C14]Catalytic dehydrogenations of ethane and propane in which activity improves with carbon deposition
○Shigeru Sugiyama1, Akihiko Koizumi1, Takahisa Iwaki1, Naohiro Shimoda1, Yuki Kato2, Wataru Ninomiya2(1. Tokushima University, 2. Mitsubishi Chemical Co.)
Keywords:
dehydrogenation,carbon deposition,nickel catalyst
In a normal catalytic dehydrogenation, the catalytic activity is significantly reduced over time-on-stream due to carbon deposition formed during the reaction. In the present presentation, it was founf that, when a dehydrogenations of ethane and propane were carried out using a nickel oxide catalyst supported on γ-alumina, the dehydrogenation activity was significantly improved with time-on-stream at a specific loading of nickel oxide. We will report the results of detailed analysis of carbon deposition, nickel dispersion, etc., which are the active factors.