[A1444-1am] 07. Inorganic Chemistry

10:00 AM - 10:20 AM JST(1:00 AM - 1:20 AM UTC)English

[A1444-1am-04] Geometric Effects of π-Basicity of Open Metal Sites in Metal–Organic Frameworks for Ambient Temperature Hydrogen Storage

○Yuto Yabuuchi^1,2,3, Hiroyasu Furukawa^1,2,3, Kurtis M. Carsh^1,3, Ryan Klein^4,5, Nikolay Tkachenko^1,2, Adrian J. Huang^1,2,3, Craig Brown^5,6, Martin Head-Gordon^1,2, Jeffrey R. Long^1,2,3 (1. University of California, Berkeley, 2. Lawrence Berkeley National Laboratory, 3. Institute for Decarbonization Materials, 4. National Renewable Energy Laboratory, 5. National Institute for Standards and Technology, 6. University of Delaware)

Keywords:

Metal–Organic Frameworks,Hydrogen Storage,π-Backbonding,Geometric Effects,Coordinatively Unsaturated Metal Sites