[R2-04]Structural change of Al-bearing CaTiO3 perovskite
*TAKAYA NAGAI1, Naoki Takakura1, Yosuke Matsumoto1, Xianyu Xue2(1. Hokkaido Uni. Sci., 2. Okayama Uni. IPM)
Keywords:
Al-bearing CaTiO_3-perovskite,morphotropic transition,XRD,NMR
Structure change of Al-bearing CaTiO3 -perovskite synthesized by the conventional solid-state reaction method was investigated. Chemical composition of Al-bearing CaTiO3 -perovskite showed that Al exchanges Ti and the solubility of the Al component is up to about 25 mol%. XRD patterns indicated a series of morphotropic transition from orthorhombic to cubic via tetragonal. NMR spectra showed Al occurring in octahedral, pentahedral and tetrahedral sites.
