2019 Annual Meeting

2019 Annual Meeting

Mar 20 - Mar 22, 2019Ibaraki University Mito Campus
Atomic Energy Society of Japan
2019 Annual Meeting

2019 Annual Meeting

Mar 20 - Mar 22, 2019Ibaraki University Mito Campus

[2B09]Investigation of platinum group compounds generated in the vitrification process(2) Change of chemical form of generated palladium compounds

*Takayuki Nagai1, Yoshihiro Okamoto1, Hideaki Shiwaku1, Daisuke Akiyama2, Nobuaki Sato2(1. JAEA, 2. IMRAM, Tohoku Univ.)

Keywords:

vitrification,palladium,rare earth,TG-DTA,XRD,XAFS

PdO reacts to NaNO3 and rare earth nitrates and Pd compounds is generated in a vitrification process. The reduction behavior of Pd(NO3)2, the synthesis of Pd compounds with Pd(NO3)2 and rare earth nitrates at high temperature and chemical reaction of Pd compounds in a molten borosilicate glass were confirmed in this study.