Hiroshima Conv. of JPI (54th Petroleum-Petrochemical Symposium of JPI)
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Presentation Information

4:30 PM - 4:45 PM JST(7:30 AM - 7:45 AM UTC)English

[2B18]Precision stereospecific synthesis of functionalized bottlebrush ROMP polymers by (arylimido)vanadium(V)-alkylidene catalysts

○Kanticha Jaiyen1, Daisuke Shimoyama1, KOTOHIRO NOMURA1 (1. Tokyo Metropolitan University)

Keywords:

Metathesis polymerization,Stereo specific synthesis,Bottlebrush Polymers

Bottlebrush polymers (BBPs) are promising materials owing to their controlled direction of side arms connected to the polymer main chain, and the method by adopting the (living) ring opening metathesis polymerization (ROMP) of norbornene macromonomers has been well known. We herein present the successful stereospecific (Z-/E- specific) synthesis of BBPs containing functionality at the side arms by using (arylimido)vanadium-alkylidene catalysts. The resultant polymers exhibit unique emission, and the detail will be introduced in the symposium.
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