[16p-P05-1~27] 12.1 Fabrications and Structure Controls

[16p-P05-21] Fabrication and electrical properties of molecular assembly electromagnetic nanocoil structures composed of TTF derivatives/F₄TCNQ complexes with chiral moieties

〇Yuki Akiyama¹, Riko Kubomoto¹, Sadafumi Nishihara^3,4, Tomoyuki Akutagawa⁵, Takayoshi Nakamura^3,6, Tsuyoshi Minami², Yoko Tatewaki¹ (1.TUAT, 2.Univ. of Tokyo, 3.Hiroshima Univ., 4.JST PRESTO, 5.Tohoku Univ., 6.Hokkaido Univ.)

Keywords:

molecular nanocoils,induced electromotive force,charge transfer complexes

The TTF derivative R-TTF-4UM, which has a chiral moiety at the end and is expected to form a helical structure, was made into a F₄TCNQ complex to give it electrical conductivity, and an attempt was made to create molecular assembly electromagnetic nanocoils on a substrate. acetonitrile solution (10 mM) were mixed 1:1 and cast onto mica, glass and PET film substrates, and then the samples were sealed and dried at room temperature for 30 minutes. AFM observation and induced EMF measurements were performed on these samples.