[19a-A34-1~8] 12.1 Fabrications and Structure Controls

10:15 AM - 10:30 AM JST(1:15 AM - 1:30 AM UTC)

[19a-A34-5] Hydrothermal synthesis of MOF with original ligand, H₄TBACPA and various metal ions

〇(M1C)Miho Kamata¹, Seiya Yokokura^1,2, Hiroki Waizumi^1,2, Toshihiro Shimada^1,2 (1.Hokkaido Univ.CSE., 2.Hokkaido Univ. Eng.)

Keywords:

Metal Organic Frameworks,photocatalysis,porous materials

Metal Organic Frameworks (MOFs) are porous materials whose crystal structures are constructed by coordination of organic linkers to metal ions. Their physical properties are modulated by selecting appropriate reagents or synthetic conditions, so they are applied in many fields such as gas adsorption, photocatalyst, transistor. 1,2,6,7-tetrakis(p-benzoic acid)cyclopenta[hi]anthrylene (H₄TBACPA) is our original organic linker, which owes narrow HOMO-LUMO gap. We utilized it to obtain MOFs with narrow band gaps. Then, Ni-H₂TBACPA, Bi-HTBACPA and Zn₂-TBACPA are synthesized, and their crystal structures are revealed by SCXRD.