Presentation Information

[20p-A32-11]Real-time Detection of Radicals at Plasma/Liquid Interfaces by Spin Trapping Method

〇Kenichi Inoue1, Takashi Kondo1, Kenji Ishikawa1, Masaru Hori1 (1.Nagoya Univ. cLPS)

Keywords:

plasma in liquid,spin trapping method,free radical

Recently, the study about reactions at plasma/liquid interfaces becomes important in plasma technology, because of the various applications of plasmas in and in contact with liquid. Electron spin resonance (ESR) with spin-trapping agents is useful for detecting short-lived free radicals reacting in liquid phase. However, the accurate quantification of radicals requires kinetics of spin-trapping agents under plasma treatment rather than in thermal equilibrium. This study investigated such kinetics by developing in situ ESR coupled to a reactor of plasmas in liquid.

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