Presentation Information

[23p-P02-20]Synthesis and Optical/Magnetic Properties of Helical One-dimensional Mn Perovskites

〇(B)Tomohide Yamada1, Yusuke Kinoshita1, Takuya Shiga2, Masayuki Nihei2, Ayumi Ishii1 (1.Waseda Univ., 2.Tsukuba Univ.)

Keywords:

One-dimensional helical structure,Single crystal,Organic-inorganic hybrid

In this study, we aim to develop new optical and magnetic functions based on one-dimensional helical structures. Here, perovskite-type hybrid crystals with a one-dimensional structure were fabricated by using Mn(II) and organic chiral molecules. The one-dimensional helical single crystals exhibit weak circular dichroism properties originating from the dd transition of Mn(II) and antiferromagnetic interactions between and within the helical chains.