Presentation Information

[24p-1BC-9]Construction of a Light-induced Multi-step and High Ion Conduction Switching Material

〇Kentaro Aoki1, Yuki Nagao1 (1.JAIST)

Keywords:

ion conductivity,light,switch

We synthesized a novel Fe (III) metal complex using a ligand with multiple light-responsive units inducing structural and pKa change. We revealed the multi-step ion conductivity switching with the on・off ratio 2.5, 110, 567 and 1.0×105 by systematic control of isomerization of light-responsive units. Moreover, we revealed the multi-step ion conductivity switching properties using the two light-responsive units.