Presentation Information
[10a-N321-6]Molecular Design of Near Infrared Two-Photon Responsive TADF Emitters and Their Application in Vacuum-Deposited OLEDs
〇Youhei Chitose1,2, Gomathi Vinayakam Mageswari1, Ryota Zenke1, Toshiharu Ide1, Shintaro Kohata1, Ja-Hon Lin3, Youichi Tsuchiya1, Chihaya Adachi1 (1.OPERA, Kyushu Univ., 2.CMS, Kyushu Univ., 3.Taipei Tech)
Keywords:
thermally-activated delayed fluorescence,two-photon absorption,molecular orbital
Thermally activated delayed fluorescence (TADF) materials are promising for a wide range of applications, including organic light-emitting diodes (OLEDs) and bioimaging. In this study, we introduced electron-withdrawing groups into a CzTRZ framework to achieve both enhanced charge-transfer character and molecular planarity, thereby enabling the coexistence of TADF and two-photon absorption (2PA) properties. This work provides a molecular design strategy for high-performance emissive materials and paves the way for next-generation bioimaging and organic optoelectronic device applications.