Presentation Information

[7a-N403-9]Development of Artificial Organic–Inorganic Hybrid Chiral Semiconductors and Detection of Chiral Electronic States

〇Tomohiro Okano1, Huang Po-jung1, Taniguchi Kouji1 (1.Science Tokyo)

Keywords:

chiral,circular photogalvanic effect,transition metal dichalcogenide

In this study, we electrochemically intercalated chiral molecular cations into the layered material MoS2 to fabricate an artificial organic-inorganic hybrid chiral semiconductor. Structural and electronic changes in the treated samples were evaluated, confirming enhanced conductivity and induced chirality. Under 405 nm circularly polarized light irradiation, distinct photocurrent responses were observed for left- and right-circularly polarized light, suggesting the generation of spin-polarized currents via the circular photogalvanic effect (CPGE), reflecting the unique electronic states of the chiral system.