Presentation Information

[8a-S202-6]Elucidation of the effect of SOP on organic photovoltaics characteristics

〇Seita Kyogoku1, Haruto Jibiki1, Masahiro Ohara2, Taku Oono3, Takahisa Shimizu3, Takeshi Okada4, Nobumichi Arai4, Hisao Ishii1,5,6, Hirohiko Fukagawa5,6 (1.GSSE Chiba Univ., 2.F.Eng. Shinshu Univ., 3.NHK STRL, 4.Tosoh Corporation, 5.CFS Chiba Univ., 6.MCRC Chiba Univ.)

Keywords:

organic photovoltaics,displacement current measurement,spontaneous orientation polarization

To enhance the performance of organic photovoltaics (OPVs), understanding the behavior of excitons and charges at organic layer interfaces is crucial. In this study, we evaluated the correlation between interfacial polarization charges and photovoltaic performance using acceptor molecules with similar molecular structures but exhibiting different potential gradients within the organic layer upon deposition. The results revealed that charge accumulation at organic interfaces, caused by negative polarization charges, deteriorates photovoltaic performance. Further discussions on the mechanism underlying this phenomenon will be presented during the session.