Presentation Information
[8p-E207-12]Detection of chirality-dependent circular photogalvanic effect in chiral supramolecular polymer
〇Masami Komoike1, Mahiro Yamamoto1, Satoru Yoshida2, Jorge Puebla1,3, Ryo Ohshima1,3, Yuichiro Ando4, Kazuo Akagi2, Masashi Shiraishi1,3 (1.Kyoto Univ., 2.Ritsumeikan Univ., 3.CSRN, Kyoto univ., 4.Osaka Metropolitan Univ.)
Keywords:
chirality,circular photogalvanic effect
As a manifestation of the interplay between structural chirality and spin, we investigated chirality-dependent circular photogalvanic effect in H-PEDOT, a chiral supramolecular polymer exhibiting both electrical conductivity and chirality. In our previous presentation, we observed a chirality-dependent photocurrent under 405 nm illumination; however, a significant contribution from circular dichroism (CD) was suggested. In the present study, photocurrent measurements were performed at 633 nm, where the contribution from CD is substantially reduced. In the presentation, the possibility of a chiral photoresponse that cannot be explained solely by CD will be discussed based on the incident-angle dependence of the photocurrent.
