講演情報

[R4-07]中性子回折とラマン分光によるNesquehoniteの化学式の再検討<font color="#FF7F27">「発表賞エントリー」</font>

*山本 弦一郎1、興野 純1、阿部 淳2、佐野 亜沙美3、服部 高典3 (1. 筑波大学、2. 総合科学研究機構、3. 日本原子力研究開発機構)

キーワード:

ネスケホン石、中性子回折、ラマン分光、水素結合

Neutron diffraction and Raman spectroscopy were performed to determine the structure and chemical formula of nesquehonite. The difference between our study and Hales et al. (2008) strongly indicates that nesquehonite can have two chemical formulas, Mg(OH)(HCO3)・2H2O and MgCO3・3H2O depending on the pH in the solution. That is, nesquehonite grown in a solution with pH around neutrality would have the chemical formula of Mg(OH)(HCO3)・2H2O, but that in a strongly alkaline solution results in the chemical formula of MgCO3・3H2O.