[[PA]-1pm] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Japanese

[[PA]-1pm-19] Stereocontrol mechanism and N-substituent effect in BINOL-phosphoric acid catalyzed enantioselective Friedel-Crafts alkylation reaction of trifluoromethyl ketimines

○Masahiro Yamanaka¹, Kunio Yamano¹, Chihiro Narita², Takahiko Akiyama² (1. Rikkyo University, 2. Gakushuin University)

Keywords:

Chiral phosphoric acid,Asymmetric Friedel-Crafts alkylation,Reversal of enantioselectivity,DFT calculation