The 105th CSJ Annual Meeting
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Academic Program [Oral A]10. Organic Chemistry -Organometallic Compounds- : Oral A

[[F]2101-4pm]10. Organic Chemistry -Organometallic Compounds-

Sat. Mar 29, 2025 1:00 PM - 2:50 PM JST
Sat. Mar 29, 2025 4:00 AM - 5:50 AM UTC
[F]2101(2101, Bldg. 2, Area 4 [1F])
Chair: Shingo Harada, Gen Onodera
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1:00 PM - 1:10 PM JST(4:00 AM - 4:10 AM UTC)Japanese

[[F]2101-4pm-01]Catalytic generation of carbene complex from 7-alkynylnorbornadiene and cationic gold complex

○Kenta Toei1, Tomi Fumiaki, Ishida Kento1, Sakai Norio1 (1. Tokyo University of Science)
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1:10 PM - 1:20 PM JST(4:10 AM - 4:20 AM UTC)Japanese

[[F]2101-4pm-02]Asymmetric Michael addition of α-substituted-cyanoacetic acids with chiral prolinolphosphine and copper catalyst

○Mai Onizawa1, Satoshi Sakai1, youhei shimizu1,2, Masaya Sawamura1,2 (1. Hokkaido University Department of Chemistry, Faculty of Science, 2. WPI-ICReDD)
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1:20 PM - 1:30 PM JST(4:20 AM - 4:30 AM UTC)Japanese

[[F]2101-4pm-03]Photoinduced copper-catalyzed asymmetric allylic acylation via kinetic resolution of secondary allylic phosphates.

○Kousei Nishimura1, Yusuke Ueda1, Yusuke Masuda1, Masaya Sawamura1,2 (1. Hokkaido University, 2. WPI-ICReDD)
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1:30 PM - 1:40 PM JST(4:30 AM - 4:40 AM UTC)Japanese

[[F]2101-4pm-04]Cu-Catalyzed C5-Selective C-H Functionalization of Indoles

○Tomohiro Isono1, Shingo Harada1, Tetsuhiro Nemoto1 (1. The Univ. of Chiba)
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1:40 PM - 1:50 PM JST(4:40 AM - 4:50 AM UTC)Japanese

[[F]2101-4pm-05]Copper-Catalyzed Regio- and Stereoselective Three-Component Coupling Reaction of Terminal Alkynes, Organoboranes, and Aldimines

○Sena Toyofuku1, Gen Onodera1, Tsutomu Fukuda1, Masanari Kimura1 (1. Nagasaki University)
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1:50 PM - 2:00 PM JST(4:50 AM - 5:00 AM UTC)

Break

2:00 PM - 2:10 PM JST(5:00 AM - 5:10 AM UTC)Japanese

[[F]2101-4pm-06]Synthesis, Structure, and Reactions of Diarylzincs Derived from Arylboronates Having ortho-Directing Groups via Boron/Zinc Exchange.

○Kazuki Hirooka1, Takuma Harada1, Jun Takaya2 (1. Science Tokyo, 2. Osaka University)
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2:10 PM - 2:20 PM JST(5:10 AM - 5:20 AM UTC)Japanese

[[F]2101-4pm-07]Tungsten-Catalyzed Synthesis of Multisubstituted Cyclopentadienes from Internal Alkynes and 3,3-Disubstituted Cyclopropenes

○Takuya Akiyama1, Akira Yamamoto1, Tao Kasahara1, Tetsuro Kusamoto1, Hayato Tsurugi2 (1. Graduate School of Engineering Sience, Osaka University, 2. Graduate School of Engineering, Osaka University)
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2:20 PM - 2:30 PM JST(5:20 AM - 5:30 AM UTC)Japanese

[[F]2101-4pm-08]Three-Component Coupling Reaction of Azobenzene and Two Different Alkynes Catalyzed by Tungsten Complexes

○Tao Kasahara1, Takuya Akiyama1, Tetsuro Kusamoto1, Hayato Tsurugi2 (1. Graduate School of Engineering Science, Osaka Univ., 2. Graduate School of Engineering, Osaka Univ.)
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2:30 PM - 2:40 PM JST(5:30 AM - 5:40 AM UTC)Japanese

[[F]2101-4pm-09]Generation of Silyllithium Species from Functionalized Silylboranes and Their Use in Oligosilane Synthesis

○Natsumi Hammyo1, Rikuro Takahashi1, Hajime Ito2,3 (1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 2. Graduate School of Engineering, Hokkaido University, 3. WPI-ICReDD, Hokkaido University)
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2:40 PM - 2:50 PM JST(5:40 AM - 5:50 AM UTC)Japanese

[[F]2101-4pm-10]Nucleophilic Substitution Reactions of Silylboranes with Leaving Group Using Organolithium Reagents and Their Mechanistic Study

○Ryohei Yamaguchi1, Rikuro Takahashi2, Hajime Ito3,4 (1. School of Engineering, Hokkaido University, 2. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 3. Graduate School of Engineering, Hokkaido University, 4. WPI-ICReDD)
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