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[19p-B1-10]Low temperature (210 °C) fabrication of Ge gate stack and its interfacial dipole analysis

〇Hajime Kuwazuru1, Taisei Aso1, Dong Wang2, Keisuke Yamamoto2 (1.IGSES, Kyushu Univ., 2.FES, Kyushu Univ.)
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Keywords:

Germanium,Gate stack,Low-temperature process

Ge is a strong candidate material for novel electronic devices such as spin MOSFET or 3D-LSI. A high-quality insulator on Ge should be formed at low temperature to realize these applications. We fabricated a Ge MOS capacitor (CAP) and n-MOSFET with a SiO2/GeO2 gate dielectric at a low temperature of 210 °C. The MOSCAP and n-MOSFET show the typical electrical characteristics without significant degradation compared with the samples fabricated at a higher temperature of 450 °C. On the other hand, we confirmed flatband voltage (VFB) significantly shifted to a positive direction. From the VFB comparison among different annealing temperatures, high-temperature annealing induces the interface dipole formation in the gate insulator, that significantly shift VFB to a negative direction. XPS analysis suggests the origin of interface dipole is oxygen atom movement at a SiO2/GeO2 interface. This information will be an important guideline for fabricating a high-quality insulator on Ge at low temperature.

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