Presentation Information

[24p-1BC-17]Thermosalient Effect: Jumping Behavior of tert-Butyl-appended Anthracene Crystal

〇Yuto Hino1, Takumi Matsuo1, Daiki Korenaga2, Tomohiro Seki2, Shotaro Hayashi1 (1.Kochi Univ. of Tech., 2.Shizuoka Univ.)

Keywords:

thermal expansion,phase transition,salient effect

Materials show a trend in expansion of their volume when the temperature increases. The thermal expansion pathways are broadly classified into two types: one is a gradual thermal expansion over a wide temperature range, and the other is a huge thermal expansion over a narrow temperature range. On the other hand, the thermal expansibility of organic crystals is of interest due to their densely packed and ordered molecular structure. However, there are few systems in which the organic crystal shape is controllable in heating and cooling. Here, we report on anthracene crystals that show giant thermal expansion in a narrow temperature range.