[14p-K506-1~17] 3.11 Nanoscale optical science and near-field optics

3:15 PM - 3:30 PM JST(6:15 AM - 6:30 AM UTC)

[14p-K506-8] Microkinetic modeling of the electron transfer reactions under strong coupling

〇Tomohiro Fukushima^1,2, Itatani Masaki¹, Murakoshi Kei¹ (1.Hokkaido Univ., 2.JST-PRESTO)

Keywords:

strong coupling,electron transfer theory

The electron transfer reaction rate at electrode-electrolyte interface depends on the electrochemical potential. The mechanisms of the multi-electron transfer reactions are generally more complicated than that of single electron transfer reactions. Recently, strong coupling, which is a vacuum field-matter interaction, has attracted much attention. It has been reported that various molecular properties and chemical reactions can be modulated. In this talk, we report a theoretical investigation of electron transfer reactions at nanostructured electrodes under strong coupling conditions.