Presentation Information

[15p-W9_325-5]X-ray Absorption Fine Structure Study of Oxidation / Reduction Effects and the Electronic State of the Infinite-Layer Cuprate Thin Films of (Ca0.85Sr0.15)1-xLaxCuO2

〇Tomoya Shimada1, Motoki Hayashi1, Riku Kagawa1, Hirotaka Okabe2, Jumpei G. Nakamura2, Hideki Kuwahara1, Ryosuke Kadono2, Kenji Ishii3, Takuya Tsuji4, Daiju Matsumura4, Masaki Fujita5, Tadashi Adachi1 (1.Sci. and Technol., Sophia Univ, 2.KEK-IMSS, 3.QST, 4.JAEA, 5.IMR, Tohoku Univ)

Keywords:

Infinite-layer cuprate,X-ray absorption fine structure,Pulsed laser deposition

To clarify the electronic states of the infinite-layer cuprate, (Ca0.85Sr0.15)1-xLaxCuO2 thin films were grown on LSAT substrates by pulsed laser deposition, followed by oxidation and reduction annealing. Electrical resistivity and X-ray absorption fine structure measurements revealed that holes were doped by excess oxygen in the as grown film with x = 0. In contrast, for x = 0.10, holes doped by excess oxygen in the as-grown film compensated for the electrons introduced by La substitution, and the removal of excess oxygen by reduction annealing resulted in the decrease in the electrical resistivity.