[28-15-pm] Chemical reaction development, mechanistic analysis, computational chemistry 5 | The 145th Annual Meeting of the Pharmaceutical Society of Japan (Fukuoka)

The 145th Annual Meeting of the Pharmaceutical Society of Japan (Fukuoka)

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Oral Presentation(A) Pharmaceutical Chemistry

[28-15-pm]Chemical reaction development, mechanistic analysis, computational chemistry 5

Fri. Mar 28, 2025 2:20 PM - 4:13 PM JST
Fri. Mar 28, 2025 5:20 AM - 7:13 AM UTC

Room 15 (MARINE MESSE FUKUOKA Hall B: Conference Room1-1 [2F])

Chair: Yoshihiro Onishi, Hiroshi Naka

2:20 PM - 2:32 PM JST(5:20 AM - 5:32 AM UTC)

[28-15-pm01S]Intramolecular radical cyclization using 1,1-difluoroethoxyaryl

○Yua Sakamoto¹, Misaki Ochiai¹, Yukiko Karuo¹, Shoki Hoshikawa¹, Atsushi Tarui¹, Kazuyuki Sato¹, Kentaro Kawai¹, Masaaki Omote¹ (1. Faculty of Pharmaceutical Sciences, Setsunan University)

2:32 PM - 2:44 PM JST(5:32 AM - 5:44 AM UTC)

[28-15-pm02S]Double intramolecular Michael addition and intramolecular allylic nucleophilic substitution reactions using the unique reactivity of 1,4-bissiloxy-1,3-cyclopentadiene motifs

○Misora Ono¹, Makoto Kobayashi¹, Naoki Kanoh^2,3, Seiichi Nakamura¹, Kazutada Ikeuchi^2,3 (1. Grad. Sch. Pharm. Sci., Nagoya City Univ., 2. Sch. Pharm., Hoshi Univ., 3. Inst. Med. Chem., Hoshi Univ.)

2:44 PM - 2:56 PM JST(5:44 AM - 5:56 AM UTC)

[28-15-pm03S]Nucleophilic substitution at a quaternary carbon center

○Shunsuke Matsui¹, Tomoyuki Yoshimura², Shohei Hamada¹, Jun-ichi Matsuo¹ (1. Sch. Pharm. Sci., Kanazawa Univ., 2. Sch. Pharm. Sci., International Univ. Health and Welfare)

2:56 PM - 3:08 PM JST(5:56 AM - 6:08 AM UTC)

[28-15-pm04S]Rapid assessment of functional group tolerance in ester synthesis using functional group evaluation kit

○Chihiro Iwashita¹, Daisuke Kanamori¹, Takashi Ohshima², Hiroyuki Morimoto¹ (1. Grad. Sch. Engineering, Kyutech, 2. Grad. Sch. Pharm. Sci., Kyushu Univ.)

3:08 PM - 3:13 PM JST(6:08 AM - 6:13 AM UTC)

Break

3:13 PM - 3:25 PM JST(6:13 AM - 6:25 AM UTC)

[28-15-pm05S](S)-Convergent DKR for synthesis of esters using native lipase in Pickering emulsion

○Tomoya Nishio¹, Shuji Akai¹, Kyohei Kanomata¹ (1. Grad. Sch. Pharm. Sci., Osaka Univ.)

3:25 PM - 3:37 PM JST(6:25 AM - 6:37 AM UTC)

[28-15-pm06S]Catalytic synthesis of N-methyl secondary amides using aqueous methylamine by diboronic acid anhydride catalysis

○Hinata Iwasawa¹, Naoya Takahashi², Naoyuki Shimada¹ (1. Department of Chemistry, Nihon Univ., 2. Department of Pharmaceutical Sciences, Kitasato Univ.)

3:37 PM - 3:49 PM JST(6:37 AM - 6:49 AM UTC)

[28-15-pm07S]Direct catalytic transformations of carboxylic acids enabled by novel ketone photocatalysis

○Hayate Sano¹, Yuki Goto¹, Hiroki Hayashi², Kenji Yamashita¹, Yoshitaka Hamashima¹ (1. Grad. Sch. Pharm. Sci., Univ. Shizuoka, 2. WPI-ICReDD., Hokkaido Univ.)

3:49 PM - 4:01 PM JST(6:49 AM - 7:01 AM UTC)

[28-15-pm08S]Catalytic asymmetric 1,3-polyol synthesis using unprotected cyclic hemiacetal aldols

○Yusuke Nakamura¹, Hiroyasu Nakao¹, MD Mahamudul Hassan Mirja¹, Moe Toyobe¹, Harunobu Mitsunuma¹, Motomu Kanai¹ (1. Grad. Sch. Pharm. Sci.)

4:01 PM - 4:13 PM JST(7:01 AM - 7:13 AM UTC)

[28-15-pm09S]Synthesis of hypervalent bromine(III) compounds by in-situ oxidation with sp-hybridized nitrogen Lewis acids

○Tomohiro Fujino¹, Tadashi Hydo², Yuko Otani¹, Kentaro Yamaguchi², Tomohiko Ohwada¹ (1. Grad. Sch. Pharm. Sci., The Univ. of Tokyo, 2. Kagawa Sch. Pharm. Sci., Tokushima Bunri Univ.)

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