講演情報
[1B11]Selective carbon-carbon bond cleavage of glucose to C4 and C2 carbohydrate fragments in ethanol by zeolite-supported Niobium oxide catalyst
○Shamayil Salim Al Hajri1, Navya Subray Bhat1, Shi Quan1, Ryota Osuga1, Satoshi Suganuma1, Kiyotaka Nakajima1 (1. Institute for Catalysis, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021, Japan)
キーワード：
Biomass conversion、Solid Catalyst、Retro-Aldolization
We have reported that a mixture of niobium oxide and zeolite can catalyze the retro-aldolization of glucose and the subsequent acetalization of its products efficiently. In this study, we focus on the supported niobium oxide catalysts to further improve the product yield by optimization of niobium loadings and the choice of zeolite topology. We examined MOR, FAU, MFI, and FER-type zeolite-supported niobium catalysts, and found that MFI (Si/Al = 80) gives excellent yield/selectivity toward C4 and C2 carbohydrates under optimized reaction conditions.