[[F]2102-1am] 10. Organic Chemistry -Organometallic Compounds- | The 105th CSJ Annual Meeting

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Academic Program [Oral A]10. Organic Chemistry -Organometallic Compounds- : Oral A

[[F]2102-1am]10. Organic Chemistry -Organometallic Compounds-

Wed. Mar 26, 2025 9:00 AM - 11:40 AM JST
Wed. Mar 26, 2025 12:00 AM - 2:40 AM UTC

[F]2102(2102, Bldg. 2, Area 4 [1F])

9:00 AM - 9:10 AM JST(12:00 AM - 12:10 AM UTC)Japanese

[[F]2102-1am-01]Catalytic Synthesis of Vinylic Isonitriles with Fluoroalkyl Groups

○Takuya Nakamura¹, Mizuki Ichihashi¹, Taiga Yurino^2,3, Takeshi Ohkuma^2,3 (1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, 2. Faculty of Engineering, Hokkaido University, 3. Frontier Chemistry Center)

9:10 AM - 9:20 AM JST(12:10 AM - 12:20 AM UTC)Japanese

[[F]2102-1am-02]Palladium-Catalyzed Synthesis of Fluorene Derivatives Involving Pd/Si Exchange

○Daigo Hayashi¹, Ryo Shintani¹ (1. Graduate School of Engineering Science, Osaka University)

9:20 AM - 9:30 AM JST(12:20 AM - 12:30 AM UTC)Japanese

[[F]2102-1am-03]Preparation of Anion Moiety-tethered Phosphine Ligands for Palladium Catalysts in Cross-coupling Reaction

○Shintaro Dozen¹, Tatsuhiko Yoshino³, Kousuke Higashida², Shigeki Matsunaga^2,4 (1. Kyoto Univ. , 2. Kyoto Univ., 3. Kyoto Univ. , 4. Hokkaido Univ.)

9:30 AM - 9:40 AM JST(12:30 AM - 12:40 AM UTC)Japanese

[[F]2102-1am-04]Palladium-Catalyzed Remote Arylative Substitution of Internal Alkenes and Its Unique Regioselectivity

○Masataka Nishikawa¹, Fumitoshi Kakiuchi¹, Takuya Kochi¹ (1. Keio University)

9:40 AM - 9:50 AM JST(12:40 AM - 12:50 AM UTC)Japanese

[[F]2102-1am-05]Access to Unsymmetrical Benzidinium Derivatives by Palladium-Catalyzed Suzuki–Miyaura Coupling of Cationic Aryl Boronic Esters

○Kamemura Kohei¹, Yushu Jin², Takanori Matsuda² (1. Tokyo Univ. of Scienece, Faculty of Science Division II, 2. Tokyo Univ. of Scienece, Faculty of Science Division I)

9:50 AM - 10:00 AM JST(12:50 AM - 1:00 AM UTC)

Break

10:00 AM - 10:10 AM JST(1:00 AM - 1:10 AM UTC)Japanese

[[F]2102-1am-06]Selective Isomerization of Terminal Alkene via Nickel/Photoredox Co-catalysis

○Kazuki Tamiya¹, Wataru Sasaki, Kosuke Higashida¹, Tatsuhiko Yoshino², Shigeki Matsunaga^1,3 (1. Kyoto University, 2. Kyoto University Hakubi, 3. Hokkaido University)

10:10 AM - 10:20 AM JST(1:10 AM - 1:20 AM UTC)Japanese

[[F]2102-1am-07]Nickel-Catalyzed Arylalkoxylation of Biphenylene C–C Bonds Based on Electrophilic Etherification

○Takeru Inoue¹, Kosuke Yasui¹, Koji Hirano¹ (1. Osaka University)

10:20 AM - 10:30 AM JST(1:20 AM - 1:30 AM UTC)English

[[F]2102-1am-08]Designing Directing Groups in Poly(phenylene sulfide)s: Nickel-Catalyzed Depolymerization and Tailored Physical Properties

○Satoshi Ogawa¹, Namiki Takenaka¹, Yu-I Hsu^1,2, Hiroshi Uyama¹, Mamoru Tobisu^1,2 (1. Graduate School of Engineering, Osaka University, 2. ICS-OTRI, Osaka University)

10:30 AM - 10:40 AM JST(1:30 AM - 1:40 AM UTC)Japanese

[[F]2102-1am-09]Design and Synthesis of New PN Chiral Ligands for Asymmetric Catalysis

○Daishi Hiramatsu¹, Takuya Kurahashi¹ (1. Kwansei Gakuin University)

10:40 AM - 10:50 AM JST(1:40 AM - 1:50 AM UTC)Japanese

[[F]2102-1am-10]Nickel-Catalyzed Reductive Cross-Coupling Reaction of Aldehydes with Alkenyl Halides

○Shuto Odagaki¹, Ko Sudo, kosuke Kawabe, Takuya Kurahashi¹ (1. Kwansei Gakuin University)

10:50 AM - 11:00 AM JST(1:50 AM - 2:00 AM UTC)

Break

11:00 AM - 11:10 AM JST(2:00 AM - 2:10 AM UTC)Japanese

[[F]2102-1am-11]Deprotonative generation of alyllithium and transmetalation to boron for synthesis of poly(1,3-phenylene) by cross-coupling polymerization

○Shuichi Ikeda¹, Farid Fithrie bin Zainal Annuar¹, Kentaro Okano¹, Atsunori Mori² (1. Department of Chemical Science and Engineering, Kobe University, 2. Research Center for Membrane and Film Technology, Kobe University)

11:10 AM - 11:20 AM JST(2:10 AM - 2:20 AM UTC)Japanese

[[F]2102-1am-12]Alkyne cross-addition reaction catalyzed by palladium amidinate complexes

○Shoya Miyazaki¹, Yuzuki Fukuda¹, Naofumi Tsukada¹ (1. Shizuoka University)

11:20 AM - 11:30 AM JST(2:20 AM - 2:30 AM UTC)Japanese

[[F]2102-1am-13]Development of A Highly Efficient Catalyst for Direct Arylation Using Aryl Triflates

○Shunta Sakai^1,2, Hitoshi Hanamura¹, Rieko Fujita¹, Ken-ichi Tada¹, Masayuki Wakioka¹ (1. SCRI, 2. Graduate School of Science, Kitasato Univ.)

11:30 AM - 11:40 AM JST(2:30 AM - 2:40 AM UTC)Japanese

[[F]2102-1am-14]Pd-Catalyzed C=C Bond Cleaving Difunctionalization of Cyclic Alkenes

○Ryotaro SHIRAI¹, Kei MUTO², Junichiro YAMAGUCHI¹ (1. Waseda University, 2. Nagoya University)

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