[[F]2402-1am] 15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- | The 105th CSJ Annual Meeting

Session Details

Academic Program [Oral A]15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology- : Oral A

[[F]2402-1am]15. Organic Chemistry -Aliphatic and Alicyclic Compounds, and New Synthetic Technology-

Wed. Mar 26, 2025 9:00 AM - 11:40 AM JST
Wed. Mar 26, 2025 12:00 AM - 2:40 AM UTC

[F]2402(2402, Bldg. 2, Area 4 [4F])

9:00 AM - 9:10 AM JST(12:00 AM - 12:10 AM UTC)Japanese

[[F]2402-1am-01]1,2-Addition Reaction of Organometallic Reagents to Borylsilyliminomethanes

○Atsuhisa Mitsui¹, Kazunori Nagao¹, Hirohisa Ohmiya¹ (1. ICR, Kyoto Univ.)

9:10 AM - 9:20 AM JST(12:10 AM - 12:20 AM UTC)English

[[F]2402-1am-02]Asymmetric Synthesis of Spiroisoxazolines and Zamamistatins via Chiral Hypoiodite-catalyzed Enantioselective Oxidative Dearomatization of Arenols

○Yaohan LIANG¹, Takehiro Kato¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

9:20 AM - 9:30 AM JST(12:20 AM - 12:30 AM UTC)Japanese

[[F]2402-1am-03]Chiral Organoiodine(III)-catalyzed Enantioselective Oxidative Dearomative Fluorination of Arenols

○Masato Tsukamoto¹, Shogo Yamamoto, Shunsuke Minabe¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya Univ.)

9:30 AM - 9:40 AM JST(12:30 AM - 12:40 AM UTC)Japanese

[[F]2402-1am-04]Chiral Quaternary Ammonium Hypobromite-catalyzed Enantioselective Oxidative Dearomative Azidation of Electron-deficient (Hetero)arenols

○Sho Akagawa¹, Yasuo Tsukimori¹, Takaharu Morino¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

9:40 AM - 9:50 AM JST(12:40 AM - 12:50 AM UTC)Japanese

[[F]2402-1am-05]Copper-catalyzed Aerobic Oxidative Generation of ortho-Quinone Methides and Chemoselective (4+2) Cycloadditions

○Takaharu Morino¹, Takehiro Kato, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. Nagoya University)

9:50 AM - 10:00 AM JST(12:50 AM - 1:00 AM UTC)Japanese

[[F]2402-1am-06]Chiral π–Cu(II) Complex-catalyzed Enantioselective [2π + 2δ] Cycloaddition of Bicyclobutane-1-carboxamides with Quinoxalin-2(1H)-ones

○Dingbilige Nan¹, Jianhao HUANG¹, Kazuaki Ishihara¹ (1. Nagoya University)

10:00 AM - 10:10 AM JST(1:00 AM - 1:10 AM UTC)Japanese

[[F]2402-1am-07]Development of Quaternary Ammonium Hypoiodite Catalyst for γ-selective Oxidative Coupling Reaction of α,β-unsaturated Carbonyl Compounds

○Kotaro Asada¹, Kai Matsui¹, Muhammet Uyanik¹, Kazuaki Ishihara¹ (1. The Univ. of Nagoya)

10:10 AM - 10:30 AM JST(1:10 AM - 1:30 AM UTC)

Break

10:30 AM - 10:40 AM JST(1:30 AM - 1:40 AM UTC)English

[[F]2402-1am-08]Catalytic Enantioselective Addition of Alkynyllithiums to Aliphatic Ketones

○Chenhan Wang¹, Kazuaki Ishihara¹ (1. Nagoya University)

10:40 AM - 10:50 AM JST(1:40 AM - 1:50 AM UTC)Japanese

[[F]2402-1am-09]Development of Chiral Carboxylic Acid for Asymmetric C–H Functionalization

○Ayu Maki¹, Kosuke Higashida¹, Tatsuhiko Yoshino¹, Shigeki Matsunaga^1,2 (1. Kyoto University, 2. Hokkaido University)

10:50 AM - 11:00 AM JST(1:50 AM - 2:00 AM UTC)Japanese

[[F]2402-1am-10]Dearomative asymmetric fluorination of arenes using chiral dicarboxylic acid-derived anionic phase-transfer catalyst

○Haruto Sugita¹, Yuki Matsubayashi¹, Kyosuke Fujiwara¹, Yoshihiro Miyake¹, Mio Shimogaki¹ (1. University of Hyogo)

11:00 AM - 11:10 AM JST(2:00 AM - 2:10 AM UTC)Japanese

[[F]2402-1am-11]Ether ring synthesis through asymmetric α-oxylation of ketone via silyl enol ether using chiral hypervalent iodine reagents

○Shun Kato¹, Taiki Nakanishi¹, Yuko Tsuyuguchi¹, Itadoko Takumi¹, Yoshihiro Miyake¹, Mio Shimogaki¹ (1. The Univ. of Hyogo)

11:10 AM - 11:20 AM JST(2:10 AM - 2:20 AM UTC)Japanese

[[F]2402-1am-12]Chiral hypervalent iodine catalyzed asymmetric α-oxidation of ketones to form ether rings

○Takumi Itadoko¹, Taiki Nakanishi, Yuko Tsuyuguchi, Shun Kato¹, Yoshihiro Miyake¹, Mio Shimogaki¹ (1. The University of Hyogo)

11:20 AM - 11:30 AM JST(2:20 AM - 2:30 AM UTC)Japanese

[[F]2402-1am-13]Development of sulfide synthesis by reduction of O,S-acetal using a trityl cation catalyst and a hydrosilane

○Koki Ushioda¹, Kento Ishida¹, Norio Sakai¹ (1. Tokyo University of Science)

11:30 AM - 11:40 AM JST(2:30 AM - 2:40 AM UTC)Japanese

[[F]2402-1am-14]Base-free Wittig Reaction via Ring-openingof Methylenecyclopropane by Phosphine and Its Application

○Sayami Matsumoto¹, Ikuya Shibata², Itaru Suzuki² (1. Graduate School of Engineering, Osaka University, 2. Research Center for Environmental Preservation, Osaka University)

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