Presentation Information

[20p-C402-7]Change in the free volume of highly hydrogenated DLC films with increasing temperature

〇(M1)Daisuke Niwa1, Tomohiro Mishima1, Koji Nakanishi1, Naoki Fukumuro2, Atsushi Kinomura3, Kazuhiro Kanda1 (1.LASTI,Univ.Hyogo, 2.Eng.Univ.Hyogo, 3.KURNS, Kyoto Univ.)

Keywords:

highly-hydrogenated diamond-like carbon films,Thermal decomposition

The H-DLC film has a low friction coefficient in a vacuum and is expected to be used as a solid lubricant in artificial satellites and vacuum chambers. In this study, the H-DLC film was heated to several temperatures, and the thermal decomposition process was discussed from the change in the free volume. As a result, the positron annihilation lifetime and S parameter increased in the sample heated to 200 ℃ compared to the sample not heated, decreased between 360 ℃ and 400 ℃, and increased between 400 ℃ and 450 ℃.