Presentation Information

[15p-M_124-1]Mirror Twin Boundary Formation in WSe2 by Nb Post-doping

〇(M2)Itsuki Tanaka1, Tomonori Nishimura1, Kaito Kanahashi1, Mai Nakashima2, Naoshi Kakeya2, Kohei Aso2, Yoshifumi Oshima2, Jui-Han Fu3, Vincent Tung3, Kouske Nagashio1 (1.UTokyo Material, 2.JAIST, 3.UTokyo Chem. Sys.)

Keywords:

two-dimensional material,TMDC,doping

We investigated post-doped Nb–WSe2 prepared by an intermittent-flux method using HAADF-STEM, confirming Nb substitution at W sites (up to 11.3%) and the formation of MTB loops. The MTB regions are transition-metal-rich, suggesting a substitution mechanism in which surface-adsorbed Nb diffuses and is incorporated into the lattice. Lowering the Nb flux and controlling the defect density are key to achieving higher substitution levels.