Presentation Information
[3F03]Consruction of composites consisting of metal-organic frameworks and self-assembled monolayer on Au surface for preparation of functional surfaces
*Yuto Tashiro1, Mikio Ito1, Ryo Shoji1 (1. National Institute of Technology, Tokyo College)
This research presents a method for creating functional metal-organic frameworks (MOFs) on solid surfaces. We investigated the construction of surface-mounted MOFs (SURMOFs) by combining self-assembled monolayers (SAMs) and MOFs. Using CPO-27 as the MOF and a mercaptoundecanoic acid (MUA) SAM on a gold substrate, we successfully synthesized both components under accessible ambient conditions. Our experiments confirmed the proper structure of the synthesized CPO-27-Ni powder via PXRD and Raman spectroscopy, with results consistent with previous reports. The correct formation of the MUA SAM was also confirmed via XPS and IRRAS. These findings establish a solid foundation for future SURMOF construction, demonstrating that the necessary components can be prepared under simple conditions. This approach provides a new way to impart MOF properties, such as high porosity and catalytic activity, to various solid materials.